http://esummit-msu.net/content/several-often-neglected-perspectives-energy-chemical-education
This paper is quite long and will need serious shortening and editing if it is to be included in the ES book. I have not had time to read it yet. Nevertheless, the paper represents some very careful and creative thinking about energy/entropy concepts. Wei makes the argument that, contrary to common thinking, there is no tendency to minimize energy. The Gibbs free energy should not be thought of as a competition between minimizing energy and maximizing entropy. Instead minimizing Gibbs free energy is just a version of maximizing entropy in a constant pressure and temperature environment. Gibbs free energy is simply a quantity which is measured in energy units and which decreases (for a system in a quasi constant pressure and temperature environment) whenever entropy increases (overall). This framing would suggest that the Gibbs free energy may have a very close relationship with the idea of energy spreading in a quasi constant P, T environment. I will have to think much more about this.
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